Even if it is leaking out of the system over a few days (I assume he cuts the tank off), once you turn the tank on you should have instant fuel, since it is pressurized.
Hard starting is a common problem, we normally replace the lockoff and converter together, rarely actually "test" to see which is bad. It's a good habit to replace both at the same time anyways.
I've got a lockoff and a converter if you'd need them for testing, one or the other is bad, not sure which (I think the converter was getting LPG, but none was coming out, so the lockoff should be good).
Try pulling the lines off the converter, if it's got LPG in but not out, there's your problem.
How old are they?