6.5 is a better block than the 6.2, I do not know the differances as I've never really gotten them torn down side by side.
late '99-early '00 blocks had an issue with internal web cracking and leaking coolant into the oil, which takes out the cam bearings and valvetrain. odds are if it has more than 70k on the clock it's ok, but still a gamble.
If you can find a truck with les than 120k on the odo, the injection pump (including PMD) is warranted for 120k or 11yrs, so this could be a plus for you.
If you find one that runs well and has been well maintained, you should have a good truck, many run well past the 200k range with little issue, the biggest issue is the injection pump. A NEW pump is $1200 + install. this out of warranty should you need one, it can be rebuilt cheaper.
Kevin